全文获取类型
收费全文 | 5219篇 |
免费 | 451篇 |
国内免费 | 71篇 |
专业分类
电工技术 | 30篇 |
技术理论 | 2篇 |
综合类 | 101篇 |
化学工业 | 3638篇 |
金属工艺 | 103篇 |
机械仪表 | 12篇 |
建筑科学 | 14篇 |
矿业工程 | 15篇 |
能源动力 | 633篇 |
轻工业 | 27篇 |
水利工程 | 2篇 |
石油天然气 | 410篇 |
武器工业 | 4篇 |
无线电 | 175篇 |
一般工业技术 | 467篇 |
冶金工业 | 88篇 |
原子能技术 | 14篇 |
自动化技术 | 6篇 |
出版年
2024年 | 11篇 |
2023年 | 220篇 |
2022年 | 114篇 |
2021年 | 197篇 |
2020年 | 225篇 |
2019年 | 224篇 |
2018年 | 189篇 |
2017年 | 146篇 |
2016年 | 167篇 |
2015年 | 131篇 |
2014年 | 189篇 |
2013年 | 256篇 |
2012年 | 211篇 |
2011年 | 251篇 |
2010年 | 183篇 |
2009年 | 245篇 |
2008年 | 244篇 |
2007年 | 255篇 |
2006年 | 218篇 |
2005年 | 235篇 |
2004年 | 201篇 |
2003年 | 187篇 |
2002年 | 197篇 |
2001年 | 172篇 |
2000年 | 184篇 |
1999年 | 131篇 |
1998年 | 109篇 |
1997年 | 45篇 |
1996年 | 150篇 |
1995年 | 66篇 |
1994年 | 77篇 |
1993年 | 68篇 |
1992年 | 48篇 |
1991年 | 57篇 |
1990年 | 39篇 |
1989年 | 12篇 |
1988年 | 5篇 |
1987年 | 8篇 |
1986年 | 6篇 |
1985年 | 11篇 |
1984年 | 23篇 |
1983年 | 15篇 |
1982年 | 15篇 |
1980年 | 1篇 |
1974年 | 1篇 |
1951年 | 2篇 |
排序方式: 共有5741条查询结果,搜索用时 734 毫秒
11.
《International Journal of Hydrogen Energy》2020,45(15):8640-8648
The catalytic conversion of CO2 to CH4 (Sabatier reaction) has been studied to develop an after-treatment process at vehicles exhausts. Three different formulations of Ru commercial catalysts, two in powder and one in pellets shape, were tested and characterized by means of X-ray powder diffraction, scanning electron microscopy (SEM-EDX), N2 adsorption at −196 °C and temperature-programmed reduction (TPR).Experimental results show a high CO2 conversion (XCO2 = 0.96 @ T = 280 °C) for one powder catalyst formulation whereas the other one has maximum CO2 conversion = 0.69. In both cases a high CH4 selectivity is measured. High CO2 conversion (XCO2 = 0.92 @ T = 300 °C) is obtained also with pellet catalysts but only at lower GHSV values. The different behavior of the catalysts was ascribed to the different physicochemical properties and the key parameters for the application development of the process were identified. In particular, the possibility to use pellets or monolithic reactors, thus minimizing the pressure drops in the reactor, makes possible a commercial application in the treatment of vehicles exhausts. 相似文献
12.
13.
《能源学会志》2020,93(6):2381-2387
To enhance the activity of catalysts for CO removal, the perovskite-type catalysts La1-xSrxCoO3 (x = 0, 0.2, 0.4, 0.6, and 0.8) with different Sr2+ doping amount were synthesized by flame spray synthesis (FSS) method. The perovskite-type catalyst synthesized by FSS has a much larger specific surface area (SSA) than that prepared by other conventional methods. The SSA of catalyst increases with the increase of Sr2+ doping amount and the SSA of La0.2Sr0.8CoO3 reaches 31.65 m2/g. Compared with other conventional methods, FSS method significantly improves the activity of catalyst and makes it close to the performances of catalysts with surface modification. The substitution of La3+ by Sr2+ promotes the generation of secondary phase Co3O4 and SrCO3. The catalytic activity of La1-xSrxCoO3 increases with the addition of Sr2+, which results from the increasing active sites and oxygen vacancies. Interestingly, La0.4Sr0.6CoO3 performs the highest activity for CO oxidation and the CO conversion reaches 50% at 148.6 °C and 90% at 165.9 °C. The oxidation of CO over La1-xSrxCoO3 catalyst may follow a combination of MvK and L-H mechanisms according to the experimental results of H2-TPR. Moreover, the catalyst exhibits good catalytic activity in consecutive oxidation cycles. In consecutive oxidation experiments with La0.4Sr0.6CoO3, the CO conversion reaches 50% at 168.8 °C and 90% at 197.8 °C in the eighth oxidation cycle. These results prove that FSS method can further improve the activity of catalysts and is suitable for the preparation of efficient catalysts. 相似文献
14.
Effect of Supports and Promoters on the Performance of Ni-Based Catalysts in Ethanol Steam Reforming
Thanh Khoa Phung Thong Le Minh Pham Anh-Nga T. Nguyen Khanh B. Vu Ha Ngoc Giang Tuan-Anh Nguyen Thanh Cong Huynh Hong Duc Pham 《化学工程与技术》2020,43(4):672-688
Ethanol steam reforming (ESR) is one of the potential processes to convert ethanol into valuable products. Hydrogen produced from ESR is considered as green energy for the future and can be an excellent alternative to fossil fuels with the aim of mitigating the greenhouse gas effect. The ESR process has been well studied, using transition metals as catalysts coupled with both acidic and basic oxides as supports. Among various reported transition metals, Ni is an inexpensive material with activity comparable to that of noble metals, showing promising ethanol conversion and hydrogen yields. Additionally, different promoters and supports were utilized to enhance the hydrogen yield and the catalyst stability. This review summarizes and discusses the influences of the supports and promoters of Ni-based catalysts on the ESR process. 相似文献
15.
16.
《International Journal of Hydrogen Energy》2020,45(49):26238-26253
The demands for high-purity hydrogen required in fuel-cell applications impose new goals and challenges for design of well performing water-gas shift (WGS) catalysts. Gold-based catalysts have exhibited high activity in the WGS reaction at low temperature. Preparation of appropriate and economically viable supports with complex composition by various synthesis procedures is an attractive approach to WGS performance improvement. The effect of two different preparation methods (wet impregnation or mechanical mixing) and ceria content (10, 20 or 30 wt%) on textural, structural, surface and reductive properties and WGS activity of gold catalysts was studied. Additionally, the role of Y2O3 as a promoter of ceria was examined. Long-term stability test was carried out at 260 °C over the most active catalyst. The composition of the best performing sample (composed of about 70 wt% alumina), prepared by mechanical mixing, was considered promising in case of practical applications because of its cost efficiency. The combination of gold nanoparticles and alumina supported Y-doped ceria proved an advantageous approach for developing new catalytic formulations with high effectiveness in clean hydrogen production. 相似文献
17.
Supported metal catalysts, particularly noble metals supported on SiO2, have attracted considerable attention due to the importance of the silica–metal interface in heterogeneous catalysis and in electronic device fabrication. Several important issues, e.g., the stability of the metal–oxide interface at working temperatures and pressures, are not well-understood. In this review, the present status of our understanding of the metal–silica interface is reviewed. Recent results of model studies in our laboratories on Pd/SiO2/Mo(1 1 2) using LEED, AES and STM are reported. In this work, epitaxial, ultrathin, well-ordered SiO2 films were grown on a Mo(1 1 2) substrate to circumvent complications that frequently arise from the silica–silicon interface present in silica thin films grown on silicon. 相似文献
18.
19.
G. Murali Dhar B. N. Srinivas M. S. Rana Manoj Kumar S. K. Maity 《Catalysis Today》2003,86(1-4):45-60
Support effects form important aspect of hydrodesulfurization (HDS) studies and mixed oxide supports received maximum attention in the last two decades. This review will focus attention on studies on mixed oxide supported Mo and W catalysts. For convenience of discussion, these are divided into Al2O3 containing mixed oxide supports, TiO2 containing mixed oxide supports, ZrO2 containing mixed oxide supports and other mixed oxide supports containing all the rest. TiO2 containing mixed oxides received maximum attention, especially TiO2–Al2O3 supported catalysts. A brief discussion about their prospects for application to ultradeep desulfurization is also included. An overview of the available literature with emphasis on research carried out in our laboratory form the contents of this publication. 相似文献
20.
Hydroprocessing catalysts based on Ni, Co, Mo and W are used in various refinery processing applications where several deactivation mechanisms become of importance (coke formation, active phase sintering, metals deposition, poisoning) in the catalyst's life cycle. The life cycle of commercial hydroprocessing catalysts is very complex and includes the catalyst production, sulfidation, use, oxidative regeneration followed by re-sulfidation and reuse or, if reuse is not possible, recycling or disposal. To understand the changes in catalyst properties taking place during a life cycle, the catalyst quality in the different stages can be best monitored by using advanced analytical techniques. The catalyst's life cycle is further complicated by numerous technical, environmental and organizational issues involved. In principle, different companies can be involved in each of the life cycle steps. Leading catalyst manufacturers, together with specialized firms, offer refineries a total catalyst management concept, starting with the purchase of the fresh catalyst and ending with its final recycling or disposal. Total catalyst management includes a broad range of services, ensuring optimal timing during the change-out process, reliable, smooth and safe operations, minimal downtime and maximum catalyst and unit performance. 相似文献